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2,3-Pentanedione

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General Description
    Synonyms: acetyl propanal; acetyl propionyl; ß,γ-dioxopentane; beta, gamma-dioxopentane; 2,3-pentadione

    OSHA IMIS Code Number: P110

    Chemical Abstracts Service (CAS) Registry Number: 600-14-6

    NIOSH, Registry of Toxic Effects (RTECS) Identification Number: SA1850000

    Department of Transportation Regulation Numbers (49 CFR 172.101): UN 1224 (ketones liquid n.o.s.) and UN 1993 (flammable liquid)

    Chemical Description and Physical Properties: yellow to green-yellow liquid with a butter odor
      molecular formula: C5H8O2
      molecular weight: 100.12
      boiling point: 110-112°C
      melting point: -52°C
      vapor pressure: 2.67 kPa @ 20°C
    Potentially hazardous incompatibilities: heat; electrostatic charge; oxidizing agents; reducing agents; strong bases
Health Factors
    Potential symptoms: eye, skin and respiratory irritant

    Health Effects: may be harmful if inhaled as it causes respiratory tract irritation; causes skin irritation; causes eye irritation; may be harmful if swallowed

    Affected organs: skin, eyes, respiratory system,
Monitoring Methods used by OSHA
    Laboratory Sampling/Analytical Method:

    • sampling media: Two specially dried Silica Gel Tubes in series. Each tube has a single 600-mg 20/40 mesh section and a glass-fiber filter, the filter faces forward when sampling. SKC 226-183, or equivalent. Use an opaque tube holder or wrap tubes with aluminum foil or other opaque material while sampling.
      analytical solvent: (95:5) ethanol:water
      maximum volume: 9 Liters   minimum flow rate: 0.05 L/min for long-term sampling; 3 liters at 0.2 L/min for short-term sampling.
      current analytical method: Gas Chromatography; GC/FID
      method reference: OSHA SLTC In-House File
      method classification: Not Validated
      note: Separate the two tubes and cap both ends of each tube as soon as possible after sampling. Individually seal the two tubes. Protect tubes from light after sampling.

    Bulk method: GC/FID

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