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Propane Safety and Health Topics:
Propane

General Description
    Synonyms: Dimethyl methane; LPG

    OSHA IMIS Code Number: 2150

    Chemical Abstracts Service (CAS) Registry Number: 74-98-6

    NIOSH, Registry of Toxic Effects (RTECS) Identification Number: TX2275000

    Department of Transportation Regulation Number (49 CFR 172.101) and Guide: 1075 115; 1978 115

    NIOSH Pocket Guide to Chemical Hazards, Propane: chemical description, physical properties, potentially hazardous incompatibilities, and more

    Related Chemical:
Exposure Limits
    OSHA Permissible Exposure Limit (PEL) for General Industry: 29 CFR 1910.1000 Z-1 Table -- 1000 ppm, 1800 mg/m3 TWA

    American Conference of Governmental Industrial Hygienists (ACGIH) Threshold Limit Value (TLV): 2500 ppm, 4508 mg/m3 TWA

    National Institute for Occupational Safety and Health (NIOSH) Recommended Exposure Limit (REL): 1000 ppm, 1800 mg/m3 TWA
Health Factors
    NIOSH Immediately Dangerous To Life or Health Concentration (IDLH): 2100 ppm (lower explosive limit)

    Potential symptoms: Dizziness, disorientation (confusion), excitation (hallucinations, euphoria); nausea, vomiting; unconsciousness; cardiac arrest (asphyxia); frostbite (contact with liquid ); long-term intermittent exposure to high concentrations can cause nosebleeds, rhinitis, oral and nasal ulcerations, conjunctivitis, bloodshot eyes, anorexia, weight loss, lethargy, fatigue and damage to the CNS.

    Health Effects: Explosive (HE18); CNS effects (HE7); Asphyxiant (HE17)

    Affected organ: CNS

    Date Last Revised: 07/10/2003

    Literature Basis:
    • International Chemical Safety Cards (WHO/IPCS/ILO): Propane.
    • Fonseca, C.A., Auerbach, D.S. and Suarez, R.V.: The forensic investigation of propane gas asphyxiation. Am. J. Forensic Med. Pathol. 23(2): 167-169, 2002.
Monitoring Methods used by OSHA
    Laboratory Sampling/Analytical Method:

    sampling media: Two Carbosieve S-III tubes in series (130/65 mg sections)
    analytical solvent: Carbon Disulfide
    maximum volume: 5.0 Liters   maximum flow rate: 0.1 L/min
    current analytical method: Gas Chromatography; GC/FID
    method reference: OSHA Manual of Analytical Methods (OSHA PV2077)
    method classification: Partially Validated

    sampling media: Combustible Gas Meter
    method reference: NIOSH Manual of Analytical Methods (NIOSH S87)
    method classification: Fully Validated

    On-Site Sampling Techniques/Methods:

    device: Detector Tube
    manufacturer: AUER/MSA
    model/type: Propane-200, MSA P/N 804418, AUER P/N 5086-831
    sampling information: follow manufacturer’s instructions
    upper measurement limit: 4000 ppm
    detection limit: approx. 200 ppm
    overall uncertainty: unknown
    method reference: on-site air secondary (manufacturer)

    device: Detector Tube
    manufacturer: Dräger
    model/type: Hydrocarbons 0.1%/b, order no. CH 26101
    sampling information: 7 to 15 strokes
    upper measurement limit: 1.3 Vol.-%
    detection limit: approx. 0.5 Vol.-%
    overall uncertainty: 49%
    method reference: on-site air secondary (manufacturer)

    device: Detector Tube
    manufacturer: Gastec
    model/type: 103
    sampling information: 0.5 to 2 strokes
    upper measurement limit: 2.4%
    detection limit: 0.05%
    overall uncertainty: 16%
    method reference: on-site air secondary (manufacturer)

    device: Detector Tube
    manufacturer: Matheson-Kitagawa
    model/type: 8014-125SA
    sampling information: follow manufacturer’s instructions
    upper measurement limit: 0.5%
    detection limit: approx. 0.02%
    overall uncertainty: unknown
    method reference: on-site air secondary (manufacturer)

    * All Trademarks are the property of their respective owners.
 
Revised: 14 October 2003
 
 
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  Chemical Sampling Information:
  Propane
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