TRIPHENYL PHOSPHATE†

Chemical Identification

CAS # 115-86-6
Formula

C₁₈H₁₅O₄P

Synonyms

phenyl phosphate; TPP; triphenyl ester of phosphoric acid

Physical Properties

Physical description Colorless, crystalline powder with a phenol-like odor.
Boiling point 473°F at 11 mmHg Molecular weight 326.3
Freezing point/melting point 122-124°F Vapor pressure 1 mmHg at 380°F
Flash point 428°F Vapor density
Specific gravity 1.2055 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating 1 NFPA fire rating 1
NFPA reactivity rating 0 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2535
Sampling group
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0]
Sampling time*
Sampling volume (TWA)*

10-400 L

Sampling flow rate (TWA)*

1-3 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments GC-FPD
Method reference NIOSH 5038 (partially validated)
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

3 mg/m³

REL-TWA

3 mg/m³

TLV-TWA

3 mg/m³ [1992]

PEL-TWA

3 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

Y

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes: Notes:
Health factors:  See NIH-NLM PubChem. IDLH

1000 mg/m³

Carcinogenic classifications: TLV-A4 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/28/2021