DIMETHYLAMINE (ANHYDROUS)†

Chemical Identification

CAS # 124-40-3
Formula

C₂H₇N

Synonyms

N-methylmethanamine

Physical Properties

Physical description Colorless gas with an ammonia- or fish-like odor.
Boiling point 44°F Molecular weight 45.1
Freezing point/melting point -134°F Vapor pressure 1.7 atm
Flash point 20°F (liquid) Vapor density 1.56
Specific gravity 0.67 (liquid at 44°F) Ionization potential 8.24 eV
Lower explosive limit (LEL) 2.8% Upper explosive limit (UEL) 14.4%
NFPA health rating 3 NFPA fire rating 4
NFPA reactivity rating 0 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 0928
Sampling group
Sampler/Sampling media XAD-7 tube (80/40 mg) coated with 10% NBD chloride [SKC 226-96]
Sampling time*

50 min

Sampling volume (TWA)*

10 L

Sampling flow rate (TWA)*

0.2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments HPLC
Method reference OSHA 34 (fully validated)
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device Detector tube Infrared spectrophotometer
Model/Type Gastec 180 Miran 1A & 1B
Sampling information
(see manufacturer instructions)
1-60 ppm range 1.2 ppm@8.8 µm

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

10 ppm (18 mg/m³)

REL-TWA

10 ppm (18 mg/m³)

TLV-TWA

5 ppm [2013]

PEL-TWA

5 ppm (9.2 mg/m³)

PEL-STEL REL-STEL TLV-STEL

15 ppm [2013]

PEL-STEL

15 ppm (27.6 mg/m³)

PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes:

dermal sensitizer (DSEN)

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

500 ppm

Carcinogenic classifications: TLV-A4 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

0.6 ppm/100 ppm/350 ppm

Additional Resources and Literature References

Last Updated Date : 12/28/2020