IRON OXIDE FUME†
| CAS # | 1309-37-1 (ferric oxide); 1332-37-2 (iron oxide); 1345-25-1 (ferrous oxide) |
|---|---|
| Formula |
Fe₂O₃ |
| Synonyms |
ferric oxide; iron (III) oxide; ferrous oxide; iron (II) oxide |
| Physical description | Reddish-brown solid. | ||
|---|---|---|---|
| Boiling point | Molecular weight | 159.7 | |
| Freezing point/melting point | 2664°F | Vapor pressure | 0 mmHg (approx) |
| Flash point | Vapor density | ||
| Specific gravity | 5.24 | Ionization potential | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 1520 | ||
|---|---|---|---|
| Sampling group | METALSSG-2 | ||
| Sampler/Sampling media | Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0] | ||
| Sampling time* | 240-480 min |
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| Sampling volume (TWA)* | 480-960 L |
||
| Sampling flow rate (TWA)* | 2 L/min |
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| Sampling volume (STEL/Peak/C)* | |||
| Sampling flow rate (STEL/Peak/C)* | |||
| Analytical method instruments | ICP | ||
| Method reference | OSHA ID-125G (fully validated) | ||
| Notes | Results will be reported from the elemental analysis for the element only; the stated identity of the actual sample contents is based on the assumption that the material sampled is as identified by the compliance officer using available documentation of materials and processes. An elemental result provided may be converted to the desired compound by multiplying the result by the appropriate stoichiometric factor. A 91B report specific to the compound (including the stoichiometric conversion) may by be provided upon request by contacting the laboratory. The stoichiometric factor for iron oxide from iron is 1.430. The physical form of a sample (dust, mist, or fume) is identified by the compliance officer using available documentation of materials and processes. Smaller filters recommended for sampling inside welding hoods |
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| Special requirements | For the entire suite of analytes listed in METALSSG-2, request analyte code 2587. |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Ghost Wipe [SKC 225-2414] |
|---|---|
| Bulk Method | This analysis is for the metal component of this analyte only. The conversion back to the analyte is a mathematical one assuming all metal present is from the analyte source. Request using analyte code I200. |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
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|---|---|---|---|---|---|---|---|
| PEL-TWA |
10 mg/m³ |
REL-TWA |
5 mg/m³ |
TLV-TWA |
5 mg/m³ (respirable particulate matter) [2005] |
PEL-TWA |
5 mg/m³ |
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
Skin notation |
N |
| Notes: | Notes: | Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
2500 mg/m³ |
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| Carcinogenic classifications: TLV-A4, IARC-3 | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - Iron oxide, spent NIOSH: Pocket Guide to Chemical Hazards - Iron Oxide Dust and Fume (as Fe) Literature References
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Last Updated Date : 06/15/2023