P-PHENYLENEDIAMINE†
| CAS # | 106-50-3 |
|---|---|
| Formula |
C₆H₈N₂ |
| Synonyms |
| Physical description | White to slightly red, crystalline solid. | ||
|---|---|---|---|
| Boiling point | 513°F | Molecular weight | 108.15 |
| Freezing point/melting point | 295°F | Vapor pressure | <1 mmHg |
| Flash point | 312°F | Vapor density | 3.72 |
| Specific gravity | Ionization potential | 6.89 eV | |
| Lower explosive limit (LEL) | Upper explosive limit (UEL) | ||
| NFPA health rating | NFPA fire rating | ||
| NFPA reactivity rating | NFPA special instruction | ||
| Vapor hazard ratio (VHR) | |||
| Historical exceedance percentage | |||
| Target organs | |||
| Analyte code (IMIS no.) | 2042 | ||
|---|---|---|---|
| Sampling group | |||
| Sampler/Sampling media | 2 GFFs (37 mm) coated with sulfuric acid, in 3-piece cassette, separated by the ring section [SKC 225-9004] | ||
| Sampling time* | |||
| Sampling volume (TWA)* | 100 L |
||
| Sampling flow rate (TWA)* | 1 L/min |
||
| Sampling volume (STEL/Peak/C)* | |||
| Sampling flow rate (STEL/Peak/C)* | |||
| Analytical method instruments | HPLC | ||
| Method reference | OSHA 87 (fully validated) | ||
| Notes | |||
| Special requirements |
* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.
| Wipe Sampler/Sampling media | Wipe with GFF (37 mm), Type A/E [AP4003705]. |
|---|---|
| Bulk Method | Limit the amount of bulk submitted to 1 g or 1 mL. |
| Device | |||||
|---|---|---|---|---|---|
| Model/Type | |||||
|
Sampling information (see manufacturer instructions) |
|
OSHA PEL
8-hour TWA (ST) STEL (C) Ceiling Peak |
NIOSH REL
Up to 10-hour TWA (ST) STEL (C) Ceiling |
ACGIH TLV©
8-hour TWA (ST) STEL (C) Ceiling |
|||||
|---|---|---|---|---|---|---|---|
| PEL-TWA |
0.1 mg/m³ |
REL-TWA |
0.1 mg/m³ |
TLV-TWA |
0.1 mg/m³ [1988] |
PEL-TWA |
0.1 mg/m³ |
| PEL-STEL | REL-STEL | TLV-STEL | PEL-STEL | ||||
| PEL-C | REL-C | TLV-C | PEL-C | ||||
| Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
Skin notation |
Y |
| Notes: | Notes: | Notes: | Notes: | ||||
| Health factors: See NIH-NLM PubChem. | IDLH |
25 mg/m³ |
|||||
| Carcinogenic classifications: TLV-A4, IARC-3 | Notes: | ||||||
| AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3: | |||||||
Additional Resources and Literature References
|
NOAA: CAMEO Chemicals - P-Phenylenediamine NIOSH: Pocket Guide to Chemical Hazards - p-Phenylene diamine Literature References
|
Last Updated Date : 01/08/2021