HEXACHLOROETHANE†

Chemical Identification

CAS # 67-72-1
Formula

C₂Cl₆

Synonyms

carbon hexachloride; ethane hexachloride; perchloroethane

Physical Properties

Physical description Colorless crystals with a camphor-like odor.
Boiling point 368.2°F (sublimes) Molecular weight 236.7
Freezing point/melting point 368.2°F (sublimes) Vapor pressure 0.2 mmHg
Flash point Vapor density 8.16
Specific gravity 2.09 Ionization potential 11.22 eV
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 1372
Sampling group
Sampler/Sampling media CSC tube (100/50 mg) [SKC 226-01]
Sampling time*
Sampling volume (TWA)*

10 L

Sampling flow rate (TWA)*

0.01-0.2 L/min

Sampling volume (STEL/Peak/C)*
 

 

Sampling flow rate (STEL/Peak/C)*
Analytical method instruments GC-FID
Method reference NIOSH 1003 (partially validated)
Notes
 

 

Special requirements
 

 

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
 

Wipe with charcoal pad, seal in glass vial for shipment. [3M 3500]

Bulk Method
 

 

On-Site Screening Techniques

Device Infrared spectrophotometer
Model/Type Miran 1A & 1B
Sampling information
(see manufacturer instructions)
0.09 ppm@12.8 µm

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA
 

1 ppm (10 mg/m³)

REL-TWA
 

1 ppm (10 mg/m³)

TLV-TWA
 

1 ppm [1990]

PEL-TWA
 

1 ppm (10 mg/m³)

PEL-STEL
 

 

REL-STEL
 

 

TLV-STEL
 

 

PEL-STEL
 

 

PEL-C
 

 

REL-C
 

 

TLV-C
 

 

PEL-C
 

 

Skin notation
 

Y

Skin notation
 

Y

Skin notation
 

Y

Skin notation
 

Y

Notes:
 

See 29 CFR 1910.1000 Table Z-1.

Notes:
 

CARCINOGEN (Ca): REDUCE EXPOSURE TO LOWEST FEASIBLE CONCENTRATION. See Appendix A, NIOSH Potential Occupational Carcinogens.

Notes:
 

 

Notes:
 

 

Health factors:  See NIH-NLM PubChem. IDLH
 

300 ppm

Carcinogenic classifications: NTP-R, NIOSH-Ca, IARC-2B, TLV-A3, EPA-C Notes:
 

Ca

AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:
 

 

Additional Resources and Literature References

Last Updated Date : 01/28/2021