TRIORTHOCRESYL PHOSPHATE†

Chemical Identification

CAS # 78-30-8
Formula

C₂₁H₂₁O₄P

Synonyms

TCP; TOCP; tri-o-cresyl ester of phosphoric acid; tri-o-cresyl phosphate; tricresyl phosphate

Physical Properties

Physical description Colorless to pale-yellow, odorless liquid or solid (below 52°F).
Boiling point 770°F (Slight decomposition) Molecular weight 368.4
Freezing point/melting point -22-(-)13°F Vapor pressure 0.00002 mmHg at 77°F
Flash point 437°F Vapor density 12.7
Specific gravity 1.16 Ionization potential
Lower explosive limit (LEL) Upper explosive limit (UEL)
NFPA health rating 1 NFPA fire rating 1
NFPA reactivity rating 0 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 2532
Sampling group
Sampler/Sampling media Pre-assembled cassette with mixed cellulose ester filter (MCEF) 0.8 micron (25 or 37 mm) [MAWP025A0 or MAWP037A0]
Sampling time*
Sampling volume (TWA)*

2-100 L

Sampling flow rate (TWA)*

1-3 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments GC-FPD
Method reference NIOSH 5037 (partially validated)
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.1 mg/m³

REL-TWA

0.1 mg/m³

TLV-TWA

0.02 mg/m³ (inhalable fraction and vapor) [2015]

PEL-TWA

0.1 mg/m³

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

N

Skin notation

Y

Skin notation

Y

Skin notation

Y

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes:

BEI®

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

40 mg/m³

Carcinogenic classifications: Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/29/2021