DEMETON (SYSTOX)†

Chemical Identification

CAS # 8065-48-3
Formula

C₈H₁₉O₃PS₂.C₈H₁₉O₃PS₂

Synonyms

o-o-diethyl-o(and S)-2-(ethylthio)ethyl phosphorothioate mixture; Systox; Mercaptophos

Physical Properties

Physical description Amber, oily liquid with a sulfur-like odor.
Boiling point decomposes Molecular weight 258.3
Freezing point/melting point -13°F Vapor pressure 0.0003 mmHg
Flash point 113°F Vapor density heavier than air
Specific gravity 1.12 Ionization potential
Lower explosive limit (LEL) 1% Upper explosive limit (UEL) 5.3%
NFPA health rating NFPA fire rating
NFPA reactivity rating NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.)
Sampling group
Sampler/Sampling media
Sampling time*
Sampling volume (TWA)*
Sampling flow rate (TWA)*
Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments
Method reference
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

0.1 mg/m³

REL-TWA

0.1 mg/m³

TLV-TWA

0.05 mg/m³ (inhalable fraction and vapor) [1998]

PEL-TWA

0.01 ppm (0.1 mg/m³)

PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C PEL-C
Skin notation

Y

Skin notation

Y

Skin notation

Y

Skin notation

Y

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes:

BEI®

Notes:
Health factors:  See NIH-NLM PubChem. IDLH

10 mg/m³

Carcinogenic classifications: Not listed Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 12/22/2020