α-METHYL STYRENE†

Chemical Identification

CAS # 98-83-9
Formula

C₉H₁₀

Synonyms

benzoic trichloride

Physical Properties

Physical description Colorless liquid with a characteristic odor.
Boiling point 330°F Molecular weight 118.2
Freezing point/melting point -10°F Vapor pressure 2 mmHg
Flash point 129°F Vapor density 4.08
Specific gravity 0.91 Ionization potential 8.35 eV
Lower explosive limit (LEL) 1.9% Upper explosive limit (UEL) 6.1%
NFPA health rating 1 NFPA fire rating 2
NFPA reactivity rating 1 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) 1782
Sampling group
Sampler/Sampling media CSC tube (100/50 mg) [SKC 226-01]
Sampling time*
Sampling volume (TWA)*

1-30 L

Sampling flow rate (TWA)*

0.01-0.2 L/min

Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments GC-FID
Method reference NIOSH 1501 (partially validated)
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device Detector tube Infrared spectrophotometer Infrared spectrophotometer
Model/Type Matheson-Kitagawa 8014-193S Miran 1A & 1B Miran 103
Sampling information
(see manufacturer instructions)
follow mfr instructions, 10-500 ppm range 0.7 ppm@11.3 µm 0-100 ppm@11.3 µm

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA REL-TWA

50 ppm

TLV-TWA

10 ppm [2009]

PEL-TWA

50 ppm (240 mg/m³)

PEL-STEL REL-STEL

100 ppm

TLV-STEL PEL-STEL

100 ppm (485 mg/m³)

PEL-C

100 ppm (480 mg/m³)

REL-C TLV-C PEL-C
Skin notation

N

Skin notation

N

Skin notation

N

Skin notation

N

Notes:

See 29 CFR 1910.1000 Table Z-1.

Notes: Notes: Notes:
Health factors:  See NIH-NLM PubChem. IDLH

700 ppm

Carcinogenic classifications: TLV-A3 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/14/2021