BENZOYL CHLORIDE

Chemical Identification

CAS # 98-88-4
Formula

C₇H₅ClO

Synonyms

benzenecarbonyl chloride; α-chlorobenzaldehyde; benzoic acid chloride

Physical Properties

Physical description A colorless fuming liquid with a pungent odor.
Boiling point 387°F Molecular weight 140.57
Freezing point/melting point 30.2°F Vapor pressure 0.4 mmHg
Flash point 162°F Vapor density 4.88
Specific gravity 1.211 Ionization potential
Lower explosive limit (LEL) 1.2% Upper explosive limit (UEL) 4.9%
NFPA health rating 3 NFPA fire rating 2
NFPA reactivity rating 2 NFPA special instruction W: Reacts violently or explosively with water
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.)
Sampling group
Sampler/Sampling media
Sampling time*
Sampling volume (TWA)*
Sampling flow rate (TWA)*
Sampling volume (STEL/Peak/C)*
Sampling flow rate (STEL/Peak/C)*
Analytical method instruments
Method reference
Notes
Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media
Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA REL-TWA TLV-TWA PEL-TWA
PEL-STEL REL-STEL TLV-STEL PEL-STEL
PEL-C REL-C TLV-C

0.5 ppm [1992]

PEL-C

0.2 ppm (1.1 mg/m³)

Skin notation

NA

Skin notation

NA

Skin notation

N

Skin notation

N

Notes:

Not established

Notes:

Not established

Notes: Notes:
Health factors:  See NIH-NLM PubChem. IDLH

10 mg/m³

Carcinogenic classifications: IARC-2A, TLV-A4 Notes:
AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

0.3 ppm/5 ppm/20 ppm

Additional Resources and Literature References

Last Updated Date : 12/17/2020