PROPIONALDEHYDE

Chemical Identification

CAS # 123-38-6
Formula

C₃H₆O

Synonyms

methylacetaldehyde; propanal; propionic aldehyde; propyl aldehyde

Physical Properties

Physical description A clear colorless liquid with an overpowering fruity odor.
Boiling point 120°F Molecular weight 58.08
Freezing point/melting point -114°F Vapor pressure 235 mmHg
Flash point 15°F Vapor density 2
Specific gravity 0.805 Ionization potential
Lower explosive limit (LEL) 2.9% Upper explosive limit (UEL) 17%
NFPA health rating 2 NFPA fire rating 3
NFPA reactivity rating 2 NFPA special instruction
Vapor hazard ratio (VHR)
Historical exceedance percentage
Target organs

Monitoring Methods Used by OSHA

Analyte code (IMIS no.) P129
Sampling group
Sampler/Sampling media XAD-2 tube (120/60 mg) coated with 10% 2-(hydroxymethyl)piperidine [SKC 226-118]
Sampling time*

Sampling volume (TWA)*

5 L

Sampling flow rate (TWA)*

0.05 L/min

Sampling volume (STEL/Peak/C)*

Sampling flow rate (STEL/Peak/C)*

Analytical method instruments GC-FID & GC-MS
Method reference NIOSH 2539 (partially validated)
Notes

Special requirements

* All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details.

Bulk/Wipe Method

Wipe Sampler/Sampling media

Bulk Method

On-Site Screening Techniques

Device
Model/Type
Sampling information
(see manufacturer instructions)

Exposure Limits

OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
NIOSH REL
Up to 10-hour TWA
(ST) STEL
(C) Ceiling
ACGIH TLV©
8-hour TWA
(ST) STEL
(C) Ceiling
CAL/OSHA PEL
8-hour TWA
(ST) STEL
(C) Ceiling
Peak
PEL-TWA

REL-TWA

TLV-TWA

20 ppm [1998]

PEL-TWA

PEL-STEL

REL-STEL

TLV-STEL

PEL-STEL

PEL-C

REL-C

TLV-C

PEL-C

Skin notation

NA

Skin notation

NA

Skin notation

N

Skin notation

NA

Notes:

Not established

Notes:

Not established

Notes:

Notes:

Not established

Health factors: See NIH-NLM PubChem. IDLH
Carcinogenic classifications: Notes:

AIHA emergency response planning guidelines - ERPG-1/ERPG-2/ERPG-3:

Additional Resources and Literature References

Last Updated Date : 01/12/2023