- Part Number:1910
- Part Number Title:Occupational Safety and Health Standards
- Subpart:1910 Subpart Z
- Subpart Title:Toxic and Hazardous Substances
- Standard Number:
- Title:Allocation Of Label Elements (Mandatory)
- GPO Source:
Appendix C to § 1910.1200 - Allocation of Label Elements (Mandatory)
C.1 The label for each hazardous chemical shall include the product identifier used on the safety data sheet.
C.1.1 The labels on shipped containers shall also include the name, address, and telephone number of the chemical manufacturer, importer, or responsible party.
C.2 The label for each hazardous chemical that is classified shall include the signal word, hazard statement(s), pictogram(s), and precautionary statement(s) specified in C.4 for each hazard class and associated hazard category, except as provided for in C.2.1 through C.2.4.
C.2.1 Precedence of Hazard Information
C.2.1.1 If the signal word “Danger” is included, the signal word “Warning” shall not appear;
C.2.1.2 If the skull and crossbones pictogram is included, the exclamation mark pictogram shall not appear where it is used for acute toxicity;
C.2.1.3 If the corrosive pictogram is included, the exclamation mark pictogram shall not appear where it is used for skin or eye irritation;
C.2.1.4 If the health hazard pictogram is included for respiratory sensitization, the exclamation mark pictogram shall not appear where it is used for skin sensitization or for skin or eye irritation.
C.2.2 Hazard Statement Text
C.2.2.1 The text of all applicable hazard statements shall appear on the label, except as otherwise specified. The information in italics shall be included as part of the hazard statement as provided. For example: “causes damage to organs (state all organs affected) through prolonged or repeated exposure (state route of exposure if no other routes of exposure cause the hazard)”. Hazard statements may be combined where appropriate to reduce the information on the label and improve readability, as long as all of the hazards are conveyed as required.
C.2.2.2 If the chemical manufacturer, importer, or responsible party can demonstrate that all or part of the hazard statement is inappropriate to a specific substance or mixture, the corresponding statement may be omitted from the label.
C.2.3 Pictograms
C.2.3.1 Pictograms shall be in the shape of a square set at a point and shall include a black hazard symbol on a white background with a red frame sufficiently wide to be clearly visible. A square red frame set at a point without a hazard symbol is not a pictogram and is not permitted on the label.
C.2.3.2 One of eight standard hazard symbols shall be used in each pictogram. The eight hazard symbols are depicted in Figure C.1. A pictogram using the exclamation mark symbol is presented in Figure C.2, for the purpose of illustration.
| Flame | Flame Over Circle | Exclamation Mark | Exploding Bomb |
|---|---|---|---|
 Flammables Self Reactives Pyrophorics Self-heating Emits Flammable Gas Organic Peroxides Desensitized Explosives |
 Oxidizers |
 Irritant Dermal Sensitizer Acute Toxicity (harmful) Narcotic Effects Respiratory Tract Irritation HNOC (nonmandatory) |
 Explosives Self Reactives Organic Peroxides |
| Corrosion | Gas Cylinder | Health Hazard | Skull and Crossbones |
 Corrosives |
 Gases Under Pressure |
 Carcinogen Respiratory Sensitizer Reproductive Toxicity Target Organ Toxicity Mutagenicity Aspiration Toxicity |
 Acute Toxicity (severe) |
Figure C.2 – Exclamation Mark Pictogram
C.2.3.3 The exclamation mark pictogram is permitted (but not required) for HNOCs as long as the words "Hazard Not Otherwise Classified" or the letters "HNOC" appear below the pictogram.
C.2.3.4 Pictograms may only appear once on a label. If multiple hazards require the use of the same pictogram, it may not appear a second time on the label.
C.2.4 Precautionary Statement Text
C.2.4.1 There are four types of precautionary statements presented, "prevention," "response," "storage," and "disposal." The core part of the precautionary statement is presented in bold print. This is the text, except as otherwise specified, that shall appear on the label. Where additional information is required, it is indicated in plain text.
C.2.4.2 When a backslash or diagonal mark (/) appears in the precautionary statement text, it indicates that a choice has to be made between the separated phrases. In such cases, the chemical manufacturer, importer, or responsible party can choose the most appropriate phrase(s). For example, "Wear protective gloves/protective clothing/eye protection/face protection" could read "wear eye protection".
C.2.4.3 When three full stops (...) appear in the precautionary statement text, they indicate that all applicable conditions are not listed. For example, in "Use explosion-proof electrical/ventilating/lighting/.../equipment", the use of "..." indicates that other equipment may need to be specified. In such cases, the chemical manufacturer, importer, or responsible party can choose the other conditions to be specified.
C.2.4.4 When text in italics is used in a precautionary statement, this indicates specific conditions applying to the use or allocation of the precautionary statement. For example, "Use explosion-proof electrical/ventilating/lighting/.../equipment" is only required for flammable solids "if dust clouds can occur". Text in italics is intended to be an explanatory, conditional note and is not intended to appear on the label.
C.2.4.5 Where square brackets ([ ]) appear around text in a precautionary statement, this indicates that the text in square brackets is not appropriate in every case and should be used only in certain circumstances. In these cases, conditions for use explaining when the text should be used are provided. For example, one precautionary statement states: "[In case of inadequate ventilation] wear respiratory protection." This statement is given with the condition for use "– text in square brackets may be used if additional information is provided with the chemical at the point of use that explains what type of ventilation would be adequate for safe use". This means that, if additional information is provided with the chemical explaining what type of ventilation would be adequate for safe use, the text in square brackets should be used and the statement would read: "In case of inadequate ventilation wear respiratory protection." However, if the chemical is supplied without such ventilation information, the text in square brackets should not be used, and the precautionary statement should read: "Wear respiratory protection."
C.2.4.6 Precautionary statements may be combined or consolidated to save label space and improve readability. For example, "Keep away from heat, sparks and open flame," "Store in a well-ventilated place" and "Keep cool" can be combined to read "Keep away from heat, sparks and open flame and store in a cool, well-ventilated place."
C.2.4.7 Precautionary statements may incorporate minor textual variations from the text prescribed in this Appendix if these variations assist in communicating safety information (e.g., spelling variations, synonyms or other equivalent terms) and the safety advice is not diluted or compromised. Any variations must be used consistently on the label and the safety data sheet.
C.2.4.8 In most cases, the precautionary statements are independent (e.g., the phrases for explosives hazards do not modify those related to certain health hazards, and products that are classified for both hazard classes shall bear appropriate precautionary statements for both). Where a chemical is classified for a number of hazards, and the precautionary statements are similar, the most stringent shall be included on the label (this will be applicable mainly to preventive measures).
C.2.4.9 If the chemical manufacturer, importer, or responsible party can demonstrate that a precautionary statement is inappropriate to a specific substance or mixture, the precautionary statement may be omitted from the label.
C.2.4.10 Where a substance or mixture is classified for a number of health hazards, this may trigger multiple precautionary statements relating to medical response, e.g., calling a poison center/doctor/... and getting medical advice/attention. In general, the following principles should be applied:
(a) Where the classification of a substance or mixture triggers several different precautionary statements, a system of prioritization should be applied. If the same medical response statement is triggered multiple times, the label need only include one precautionary statement reflecting the response at the highest level with the greatest urgency, which should always be combined with at least one route of exposure or symptom "IF" statement.
(b) Routes of exposure, including "IF exposed or concerned," may be combined when triggered with a medical response statement. If the response statement is triggered with three or more routes of exposure, "IF exposed or concerned" may be used. However, relevant "IF" statements describing symptoms must be included in full. If a route of exposure is triggered multiple times, it need only be included once.
(c) This does not apply to "Get medical advice/attention if you feel unwell" or "Get immediate medical advice/attention" when they are combined with an "If" statement and must appear without prioritization.
C.3 Supplementary Hazard Information
C.3.1 To ensure that non-standardized information does not lead to unnecessarily wide variation or undermine the required information, supplementary information on the label is limited to when it provides further detail and does not contradict or cast doubt on the validity of the standardized hazard information.
C.3.2 Where the chemical manufacturer, importer, or distributor chooses to add supplementary information on the label, the placement of supplemental information shall not impede identification of information required by this section.
C.3.3 Where an ingredient with unknown acute toxicity is used in a mixture at a concentration ≥1%, and the mixture is not classified based on testing of the mixture as a whole, a statement that X% of the mixture consists of ingredient(s) of unknown acute toxicity (oral/dermal/inhalation) is required on the label and safety data sheet.
C.4 Requirements for Signal Words, Hazard Statements, Pictograms, and Precautionary Statements
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Pictogram Skull and crossbones |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
| 1 | Danger | Fatal if swallowed | |
| 2 | Danger | Fatal if swallowed | |
| 3 | Danger | Toxic if swallowed |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wash ...thoroughly after handling.
... Chemical manufacturer, importer, or distributor to specify parts of the body to be washed after handling. Do not eat, drink or smoke when using this product. |
If swallowed: Immediately call a poison center/doctor/...
... Chemical manufacturer, importer,or distributor to specify the appropriate source of emergency medical advice. Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. Rinse mouth. |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container or both. |
|
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
| 4 | Warning | Harmful if swallowed |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wash ... thoroughly after handling.
... Chemical manufacturer, importer, or distributor to specify parts of the body to be washed after handling. Do not eat, drink or smoke when using this product. |
If swallowed: Call a poison center/doctor/.../ if you feel unwell.
... Chemical manufacturer, importer, or distributor to specify the appropriate source of emergency medical advice. Rinse mouth. |
- |
Dispose of contents/container to...
... in accordance with local/regional/national/international regulations (to be specified). |
|
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Pictogram Skull and crossbones |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | Fatal in contact with skin | |
| 2 | Danger | Fatal in contact with skin |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not get in eyes, on skin, or on clothing.
Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing. |
If on skin: Wash with plenty of water/... ... Chemical manufacturer, importer, or distributor may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. Immediately call a poison center/doctor/... Specific treatment (see ... on this label) |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/ international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
|
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Pictogram Skull and crossbones |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 3 | Danger | Toxic in contact with skin |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wear protective gloves/protective clothing. Chemical manufacturer, importer, or distributor to specify type ofequipment where appropriate. |
If on skin: Wash with plenty of water/... ... Chemical manufacturer, importer, or distributor may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. Call a poison center/doctor/.../if you feel unwell. Specific treatment (see ... on this label) Take off immediately all contaminated clothing and wash it before reuse. |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer,or distributor to specify whether disposal requirements apply to contents, container, or both. |
|
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 4 | Warning | Harmful in contact with skin |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wear protective gloves/protective clothing Chemical manufacturer, importer, or distributor to specify type of equipment where appropriate. |
If on skin: Wash with plenty of water/... ... Chemical manufacturer, importer, or distributor may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. Call a poison center/doctor/.../if you feel unwell. Specific treatment (see ... on this label) Take off contaminated clothing and wash it before reuse. |
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Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container or both. |
|
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Pictogram Skull and crossbones |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | Fatal if inhaled | |
| 2 | Danger | Fatal if inhaled |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not breathe dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Use only outdoors or in a well-ventilated area. [In case of inadequate ventilation] wear respiratory protection. |
If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center/doctor/... Specific treatment is urgent (see ... on this label) |
Store in a well-ventilated place. Keep container tightly closed. Store locked up. |
Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container or both. |
Note: If the substance/mixture is determined to be corrosive to the respiratory tract leading to lethality, the corrosivity hazard must also be communicated with the corrosive pictogram and hazard statement "corrosive to the respiratory tract".
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Pictogram Skull and crossbones |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 3 | Danger | Toxic if inhaled |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Avoid breathing dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Use only outdoors or in a well-ventilated area. |
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call a poison center/doctor/... Specific treatment (see ... on this label) |
Store in a well-ventilated place. Keep container tightly closed. Store locked up. |
Dispose of content/container to... |
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 4 | Warning | Harmful if inhaled |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Avoid breathing dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Use only outdoors or in a well-ventilated area. |
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call a poison center/doctor/.../if you feel unwell. |
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|
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Pictogram Corrosion |
| Hazard category | Signal word | Hazard statement |  |
|---|---|---|---|
| 1A to 1C | Danger | Causes severe skin burns and eye damage |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not breathe dusts or mists. - if inhalable particles of dusts or mists may occur during use. Wash ...thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. |
If swallowed: Rinse mouth. Do NOT induce vomiting.
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water [or shower]. Wash contaminated clothing before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. Immediately call a poison center/doctor/... Specific treatment (see ... on this label) If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/ international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
Note: If the classifier determines, based on skin data, that the chemical may be corrosive to the respiratory tract, then the corrosivity hazard must also be communicated with the corrosive pictogram and hazard statement "corrosive to the respiratory tract".
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 2 | Warning | Causes skin irritation |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wash ... thoroughly after handling. ... Chemical manufacturer, importer, or distributor to specify parts of the body to be washed after handling. Wear protective gloves. |
If on skin: Wash with plenty of water/... ... Chemical manufacturer, importer, or distributor may specify a cleansing agent if appropriate, or may recommend an alternative agent in exceptional cases if water is clearly inappropriate. Specific treatment (see ... on this label) If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. |
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Pictogram Corrosion |
| Hazard category | Signal word | Hazard statement | |
|---|---|---|---|
| 1 | Danger | Causes serious eye damage |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wear eye protection/face protection. Chemical manufacturer, importer, or distributor to specify type of equipment where appropriate. |
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a poison center/doctor/... |
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Note: If the classifier determines, based on eye data, that the chemical may be corrosive to the respiratory tract, then corrosivity hazard must also be communicated with the corrosive pictogram and hazard statement "corrosive to the respiratory tract".
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 2A | Warning | Causes serious eye irritation |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wash ... thoroughly after handling. ... Chemical manufacturer, importer, or distributor to specify parts of the body to be washed after handling. Wear eye protection/face protection. |
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention. |
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Pictogram No Pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 2B | Warning | Causes eye irritation |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Wash ... thoroughly after handling. ... Chemical manufacturer, importer, or distributor to specify parts of the body to be washed after handling. |
If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
If eye irritation persists: Get medical advice/attention. |
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
| 1 (including both sub-categories 1A and 1B) | Danger | May cause allergy or asthma symptoms or breathing difficulties if inhaled |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Avoid breathing dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. [In case of inadequate ventilation] wear respiratory protection. |
If inhaled: If breathing is difficult, remove person to fresh air and keep comfortable for breathing.
If experiencing respiratory symptoms: Call a poison center/doctor/... |
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Dispose of contents/container to... ... in accordance with local/regional/national/ international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 (including both sub-categories 1A and 1B) | Warning | May cause an allergic skin reaction |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Avoid breathing dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves. |
If on skin: Wash with plenty of water/... If skin irritation or rash occurs: Get medical advice/attention. Specific treatment (see ... on this label) Take off contaminated clothing and wash it before reuse. |
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Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1A and 1B | Danger | May cause genetic defects <...> | |
| 2 | Warning | Suspected of causing genetic defects <...> | |
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< > (state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection/ ...Chemical manufacturer, importer, or distributor tospecify the appropriate personal protective equipment. |
If exposed or concerned: Get medical advice/attention. |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container or both. |
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1A and 1B | Danger | May cause cancer <...> | |
| 2 | Warning | Suspected of causing cancer <...> | |
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< > (state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection/ ...Chemical manufacturer, importer, or distributor to specify the appropriate personal protective-equipment. |
If exposed or concerned: Get medical advice/attention. |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
Note: If a Category 2 carcinogen ingredient is present in the mixture at a concentration between 0.1% and 1%, iriformation is required on the SDS for a product; however, a label warning is optional. If a Category 2 carcinogen ingredient is present in the mixture at a concentration of> 1%, both an SDS and a label is required and the information must be included on each.
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1A and 1B | Danger | May damage fertility or the unborn child <...> <<...>> | |
| 2 | Warning | Suspected of damaging fertility or the unborn child <...> <<...>> | |
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< > (state specific effect if known) | |
|
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<<...>>(state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Obtain special instructions before use.
Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection/ ...Chemical manufacturer, importer, or distributor tospecify the appropriate personal protective equipment. |
If exposed or concerned: Get medical advice/attention. |
Store locked up. |
Dispose of contents/container to... |
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Pictogram No Pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
No designated number (See Table A.7.1 in Appendix A.7) |
No signal word | May cause harm to breast-fed children |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Obtain special instructions before use.
Do not breathe dusts or mists. Avoid contact during pregnancy/while nursing. Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. |
If exposed or concerned: Get medical advice/attention. |
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
1 |
Danger | Causes damage to organs <...> <<...>> | |
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<...> (or state all organs affected if known) | |
|
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<<...>> (state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not breathe dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Wash ...thoroughly after handling. Do not eat, drink or smoke when using this product. |
If exposed: Call a poison center/doctor/... ... Chemical manufacturer, importer, or distributor to specify the appropriate source of emergency medical advice. Specific treatment (see ... on this label) |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
Note: If the chemical is determined to be corrosive to the respiratory tract, corrosive to the respiratory tract must be communicated with the hazard statement "corrosive to the respiratory tract, if inhaled" and corrosive pictogram, in lieu of current hazard statement and pictogram.
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
2 |
Warning | May cause damage to organs <...> <<...>> | |
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<...> (or state all organs affected, if known) | |
|
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<<...>> (state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not breathe dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. |
If exposed or concerned: Call a poison center/doctor/... ... Chemical manufacturer, importer, or distributor to specify the appropriate source of emergency medical advice. |
Store locked up. | Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
Note: If the substance/mixture is determined to be corrosive to the respiratory tract, corrosivity must be communicated with the hazard statement "corrosive to the respiratory tract, if inhaled" and corrosive pictogram in lieu of current hazard statement and pictogram.
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Pictogram Exclamation mark |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
3 |
Warning | May cause respiratory irritation; or | |
|
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May cause drowsiness or dizziness |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Avoid breathing dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Use only outdoors or in a well-ventilated area. |
If inhaled: Remove person to fresh air and keep comfortable for breathing.
Call a poison center/doctor/.../if you feel unwell. |
Store in a well-ventilated place. Keep container tightly closed. - if the chemical is volatile and may generate a hazardous atmosphere. Store locked up. |
Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
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Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
1 |
Danger | Causes damage to organs <...> through prolonged or repeated exposure <<...>> | |
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<...> (state all organs affected, if known) | |
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- |
- |
<<...>> (state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not breathe dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. Wash ... thoroughly after handling. Do not eat, drink or smoke when using this product. |
Get medical advice/attention if you feel unwell. Chemical manufacturer, importer, or to distributor to select medical advice or attention as appropriate. |
- |
Dispose of contents/container to... ... in accordance with local/regional/national/international regulations (to be specified). Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both. |
|
- |
- |
- |
Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
2 |
Warning | May cause damage to organs <...> through prolonged or repeated exposure <<...>> | |
|
- |
- |
<...> (state all organs affected, if known) | |
|
- |
- |
<<...>> (state route of exposure if no other routes of exposure cause the hazard) |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Do not breathe dust/fume/gas/mist/ vapors/spray. Chemical manufacturer, importer, or distributor to specify applicable conditions. |
Get medical advice/attention if you feel unwell. Chemical manufacturer, importer, or distributor to select medical advice or attention as appropriate. |
- |
Dispose of contents/container to... |
|
- |
- |
- |
Pictogram Health hazard |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
1 |
Danger | May be fatal if swallowed and enters airways |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
- |
If swallowed: Immediately call a poison center/doctor/... ... Chemical manufacturer, importer, or distributor to specify the appropriate source of emergency medical advice. Do NOT induce vomiting. |
Store locked up. |
Dispose of contents/container to... |
|
- |
- |
- |
Pictogram Exploding bomb |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
|
Unstable explosive |
Danger | Unstable explosive |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Obtain special instructions before use.
Do not subject to grinding/shock/friction/ ... Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Explosion risk. Evacuate area. DO NOT fight fire whenfire reaches explosives. Evacuate area.
|
Store in accordance with... |
Refer to manufacturer, importer, or distributor ... for information on disposal, recovery, or recycling. |
|
- |
- |
- |
Pictogram Exploding bomb |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
Division 1.1 |
Danger | Explosive; mass explosion hazard | |
| Division 1.2 | Danger | Explosive; severe projection hazard | |
| Division 1.3 | Danger | Explosive; fire, blast or projection |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep only in original packaging. Ground and /bond container and receiving equipment. Do not subject to grinding/shock/.../friction. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ .... |
In case of fire: Explosionrisk. Evacuate area.
DO NOT fight fire when fire reaches explosives. |
Store ... |
Refer to manufacturer, importer, or distributor ... for information on disposal, recovery, or recycling. |
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B. l of this section, in which case the corresponding symbol, signal word atui/or the hazard statement shall be assigned.
|
- |
- |
- |
Pictogram Exploding bomb1 |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
Division 1.4 |
Warning | Fire or projection hazard |
| Precautionary statements1 | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. - No smoking. Keep only in original packaging. Ground and /bond container and receiving equipment. Do not subject to grinding/shock/.../friction. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Explosion risk. Evacuate area. Do NOT fight fire when fire reaches explosives. - except for-explosives of division 1.4 (compatibility group S) in transport packaging. In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
Store ... ...in accordance with.... ...Chemical manufacturer, importer, or distributor to specify local/regional/national/international regulations as applicable. |
Refer to manufacturer, importer, or distributor ... forinformation on disposal, recovery, or recycling
... Manufacturer, importer,or distributor to specify appropriate source of information, in accordance with local/regional/national/international regulations asapplicable. |
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to Division 1.1 unless the hazard 1s shown to correjpond to one of the hazard categories in Appendix B. l of this section, in which case the correjponding jymbol, signal word and/or the hazard statement shall be assigned 1
|
- |
- |
- |
Pictogram No Pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
Division 1.5 |
Danger | May mass explode in fire |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. - No smoking. Keep only in original packaging. Ground and /bond container and receiving equipment. Do not subject to grinding/shock/.../friction. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives. |
Store in accordance with ... ... Chemical manufacturer, importer, or distributor to specify local/regional/ national/international regulations as applicable. |
Refer to manufacturer, importer, or distributor ... for information on disposal, recovery, or recycling. ... Manufacturer, distributor, or importer to specify appropriate source of information, in accordance with local/regional/national/ international regulations as applicable. |
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.l of this section, in which case the corresponding symbol, signal word and/or the hazard statement shall be assigned.
|
- |
- |
- |
Pictogram No Pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
Division 1.6 |
No signal word | No hazard statement |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
| None assigned | None assigned | None assigned | None assigned |
Note: Unpackaged explosives or explosives repacked in packagings other than the original or similar packaging shall have the label elements assigned to Division 1.1 unless the hazard is shown to correspond to one of the hazard categories in Appendix B.l of this section, in which case the corresponding symbol, signal word and/or the hazard statement shall be assigned.
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
|
1A |
Danger | Extremely flammable gas | |
|
1B |
Danger | Flammable gas |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
Leaking gas fire: Do not extinguish, unless leak can be place. stopped safely. In case of leakage, eliminate all ignition sources. |
Store in well-ventilated |
- |
NOTE: For flammable gas Category 1A, pyrophoric gas and Category IA, chemically unstable gas A and B, see statements below.
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
1A, Pryrophoric gas |
Danger | Extremely flammable gas | |
|
- |
- |
May ignite spontaneously if exposed to air |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case of leakage, eliminate all ignition sources. |
Store in well-ventilated place. |
- |
Note: This table lists only precautionary statements that are assigned due to the flammability and the pyrophoricity of the gas. For the other precautionary statements that are assigned based on chemical instability, see the respective tables for chemically unstable gases A and B.
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
1A, Chemically unstable gas A |
Danger | Extremely flammable gas May react explosively even in the absence of air. |
|
|
1A, Chemically unstable gas B |
Danger | Extremely flammable gas May react explosively even in the absence of air at elevated pressure and/or temperature. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
Leaking gas fire: Do not extinguish, unless leak can be stopped safely. In case of leakage, eliminate all ignition sources. |
Store in well-ventilated place. |
- |
Note: This table lists only the precautionary statements that are assigned due to the flammability and the chemical instability of the gas. For the other precautionary statements that are assigned based on pyrophoricity, see the respective table for pyrophoric gas.
|
- |
- |
- |
Pictogram No Pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
2 |
Warning | Flammable gas |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
Leaking gas fire: Do not extinguish, unless leak can be place. stopped safely. In case of leakage, eliminate all ignition sources. |
Store in well-ventilated |
- |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | Extremely flammable aerosol Pressurized container: may burst if heated. |
|
|
2 |
Warning | Flammable aerosol Pressurized container: may burst if heated. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. |
- |
Protect from sunlight. Do not expose to temperatures exceeding 122 °F ( 50 °C). |
- |
|
- |
- |
- |
Pictogram No Symbol |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 3 | Warning | Pressurized container: may burst if heated. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces,sparks,open flames and other ignition sources. No smoking. Do not pierce or burn, even after use. |
- |
Protect from sunlight. Do not expose to temperatures exceeding 122 °F ( 50 °C). |
- |
|
- |
- |
- |
Pictogram Gas Cylinder and Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
| 1 | Danger | Extremely flammable chemical under pressure May explode if heated. |
|
|
2 |
Warning | Flammable chemical under pressure May explode if heated. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. |
In case of leakage, eliminate all ignition sources. Stop leak if safe to do so. |
Protect from sunlight. Store in a well-ventilated place. |
- |
|
- |
- |
- |
Pictogram Gas Cylinder |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 3 | Warning | Chemical under pressure: may explode if heated. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. |
Stop leak if safe to do so. |
Protect from sunlight. Store in a well-ventilated place. |
- |
|
- |
- |
- |
Pictogram Flame over circle |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |  |
| 1 | Danger | May cause or intensify fire; oxidizer |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from clothing and other combustible materials. Keep valves and fittings freefrom oil and grease. |
In case of fire: Stop leak if safe to do so. |
Store in well-ventilated place. |
- |
|
- |
- |
- |
Pictogram Gas cylinder |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| Compressed gas | Warning | Contains gas under pressure; may explode if heated | |
| Liquefied gas | Warning | Contains gas under pressure; may explode if heated | |
Dissolved gas |
Warning | Contains gas under pressure; may explode if heated |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
- |
- |
Protect from sunlight. Store in a well-ventilated place. |
- |
|
- |
- |
- |
Pictogram Gas cylinder |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| Refrigerated liquefied gas | Warning | Contains refrigerated gas; may cause cryogenic burns or injury |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Wear cold insulating gloves and either face shield or eye protection. |
Thaw frosted parts with lukewarm water. Do not rub affected area. |
Store in well-ventilated place. |
- |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | Extremely flammable liquid and vapor | |
| 2 | Danger | Highly flammable liquid and vapor | |
| 3 | Warning | Flammable liquid and vapor |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat/sparks/open flames/hot surfaces.– No smoking. Ground/Bond container and receiving equipment Use explosion-proof [electrical/ventilating/lighting/ ... /] equipment. Chemical manufacturer, importer, or distributor to specify other equipment. Take action to prevent static discharge. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/[or shower]. In case of fire: Use ... to extinguish. |
Store in a well-ventilated place. Keep cool. - for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere. |
Dispose of contents/container to... |
|
- |
- |
- |
Pictogram No Pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 4 | Warning | Combustible liquid |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Use ... to extinguish. |
Store in a well-ventilated place. - for flammable liquids Category 1 and other flammable liquids that are volatile and may generate an explosive atmosphere. |
Dispose of contents/container to ... |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | Flammable solid | |
| 2 | Warning | Flammable solid |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof [electrical/ventilating/ lighting/ ... ] equipment. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Use ... to extinguish |
- |
- |
|
- |
- |
- |
Pictogram Exploding bomb |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| Type A | Danger | Heating may cause an explosion |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep cool. Ground and bond container and receiving equipment. - if electrostatically sensitive and able to generate an explosive atmosphere. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Explosion risk. |
Store in a well-ventilated place. Store at temperatures not exceeding ... °F {°C). Store separately. |
Dispose of contents/container to ... |
|
- |
- |
- |
Pictogram Exploding bomb and flame |
|
|---|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
|
| Type B | Danger | Heating may cause a fire or explosion | ||
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, /sparkst /open flames and other ignition sources. No smoking. Keep cool. Ground and bond container and receiving equipment. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. [Use ... to extinguish]. |
Store in a well-ventilated place. Store at temperatures not exceeding ... °F {°C). Store separately. |
Dispose of contents/container to ... |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
| Type C | Danger | Heating may cause a fire | |
| Type D | Danger | Heating may cause a fire | |
| Type E | Warning | Heating may cause a fire | |
| Type F | Warning | Heating may cause a fire |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, /sparkst /open flames and other ignition sources. No smoking. Keep cool. Ground and bond container and receiving equipment. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Use ... to extinguish |
Store in a well-ventilated place. except for temperature controlled self-reactive substances and mixtures or organic peroxides because condensation and consequent.freezing may take place. Store at temperatures not exceeding ... °F {°C). Store separately. |
Dispose of contents/container to ... |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
| 1 | Danger | Catches fire spontaneously if exposed to air |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. - No smoking. Do not allow contact with air. Handle and store contents under inert gas/ .... Keep container tightly closed. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Chemical manufacturer, importer, or distributor tospecify the appropriate personal protective equipment. |
If on skin: Immerse in cool water or wrap in wet bandages In case of fire: Use ... to extinguish |
- |
- |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
| 1 | Danger | Catches fire spontaneously if exposed to air |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. - No smoking. Do not allow contact with air. Handle and store contents under inert gas/ .... Keep container tightly closed. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection. Chemical manufacturer, importer, or distributor tospecify the appropriate personal protective equipment. |
If on skin: Brush off loose particles from skin. Immerse in cool water or wrap in wet bandages. In case of fire: Use ... to extinguish |
- |
- |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
| 1 | Danger | Self-heating; may catch fire | |
| 2 | Warning | Self-heating in large quantities; may catch fire |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep cool. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/... |
- |
Maintain air gap between stacks/or pallets. Protect from sunlight. Store bulk masses greater than ... kg/ ... Ibs at temperatures not exceeding ... °F {°C). Store separately. |
- |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
| 1 | Danger | In contact with water releases flammable gases, which may ignite spontaneously | |
| 2 | Danger | In contact with water releases flammable gas |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Do not allow contact with water. Handle and store contents under inert gas/ ... Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
If on skin: Brush off loose particles from skin and immerse in cool water. In case of fire: Use ... to extinguish |
Store in a dry place. Store in a closed container. |
Dispose of contents/container to... |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement |
|
| 3 | Warning | In contact with water releases flammable gas |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Handle and store contents under inert gas/ ... Protect from moistnre. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Use ... to extinguish. |
Store in a dry place. Store in a closed container. |
Dispose of contents/container to... |
|
- |
- |
- |
Pictogram Flame over circle |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | May cause fire or explosion; strong oxidizer |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from clothing and other combustible materials. Wear protective gloves /protective clothing/eye protection/face protection/hearing protection/ .... Wear fire resistant or flame retardant clothing. |
If on clothing: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. In case of fire: Use ... to extinguish. |
Store separately. |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
- |
- |
- |
Pictogram Flame over circle |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 2 | Danger | May intensify fire; oxidizer | |
| 3 | Warning | May intensify fire; oxidizer |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from clothing and other combustible materials. |
In case of fire: Use ... to extinguish. |
- |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
- |
- |
- |
Pictogram Flame over circle |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | May cause fire or explosion; strong oxidizer |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep away from clothing and other combustible materials. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... Wear fire resistant or flame retardant clothing. |
If on clothing: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. In case of fire: Use ... to extinguish. |
Store separately. |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
- |
- |
- |
Pictogram Flame over circle |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 2 | Danger | May intensify fire; oxidizer | |
| 3 | Warning | May intensify fire; oxidizer |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sonrces. No smoking. Keep away from clothing and other combustible materials. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Use ... to extinguish. - if water increases risk. ... Chemical manufacturer, importer, or distributor to specify appropriate media. |
- |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
- |
- |
- |
Pictogram Exploding bomb |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| Type A | Danger | Heating may cause an explosion |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep only in original packaging. Keep cool. Ground and bond container and receiving equipment. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: |
Store in a well-ventilated place. Protect from sunlight. Store at temperatures not exceeding ... °F {°C). Store separately. |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
- |
- |
- |
Pictogram Exploding bomb and flame |
|
|---|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
|
| Type B | Danger | Heating may cause an explosion | ||
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep only in original packaging. Keep cool. Ground and bond container and receiving equipment. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Evacuate area. |
Store in a well-ventilated place. Protect from sunlight. Store at temperatures not exceeding ... °F {°C). Store separately. |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
- |
- |
- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| Type C | Danger | Heating may cause a fire | |
| Type D | Danger | Heating may cause a fire | |
| Type E | Warning | Heating may cause a fire | |
| Type F | Warning | Heating may cause a fire |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep only in original packaging. Keep cool. Ground and bond container and receiving equipment. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Use ... to extinguish. |
Store in a well-ventilated place. Protect from sunlight. Store at temperatures not exceeding ... °F {°C). Store separately. |
Dispose of contents/container to... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container, or both |
|
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Pictogram Corrosion |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Warning | May be corrosive to metals |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep only in original packaging. |
Absorb spillage to prevent material damage. |
Store in corrosive resistant/... container with a resistant inner liner. ... Chemical manufacturer, importer, or distributor to specify other compatible materials. |
- |
|
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Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 1 | Danger | Fire, blast or projection hazard; increased risk of explosion if desensitizing agent is reduced. | |
| 2 | Danger | Fire, blast or projection hazard; increased risk of explosion if desensitizing agent is reduced. | |
| 3 | Warning | Fire, blast or projection hazard; increased risk of explosion if desensitizing agent is reduced. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid heating under confinement or reduction of the desensitizing agent. Keep wetted with ... Keep container tightly closed. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
Store in accordance with ... |
Dispose of contents/container to ... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container or both. |
|
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- |
Pictogram Flame |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| 4 | Warning | Fire hazard; increased risk of explosion if desensitizing agent is reduced. |
| Precautionary statements | |||
|---|---|---|---|
| Prevention | Response | Storage | Disposal |
|
Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid heating under confinement or reduction of the desensitizing agent. Keep wetted with ... Keep container tightly closed. Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ ... |
In case of major fire: Evacuate area. Fight fire remotely due to the risk of explosion. |
Store in accordance with ... |
Dispose of contents/container to ... Chemical manufacturer, importer, or distributor to specify whether disposal requirements apply to contents, container or both. |
|
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No pictogram |
|---|---|---|---|
| Hazard category | Signal word | Hazard statement | |
| Simple Asphyxiant | Warning | May displace oxygen and cause rapid suffocation | |
| No pictogram | |||
| Hazard category | Signal word | Hazard statement |
|---|---|---|
|
Combustible Dust2 |
Warning |
May form combustible dust concentrations in air [if small particles are generated during further processing, handling or by other means.] or May form explosible dust-air mixture [if small particles are generated duringfurther processing, handling or by other means.] Text in square brackets may be used when the material can only create a combustible dust hazard due to the creation of small particles during the processing or handling of the chemical |
- 2 1) The chemical manufacturer or importer shall label chemicals that are shipped in dust form, and present a combustible dust hazard in that form when used downstream, under paragraph (f)(l) of this section;
2) the chemical manufacturer or importer shipping chemicals that are in a form that is not yet a dust must provide a label to customers, that follows the approach described under paragraph (f)(4) of this section if, under normal conditions of use, the chemicals are processed in a downstream workplace in such a way that they present a combustible dust hazard; and
3) the employer shall follow the workplace labeling requirements under paragraph (f)(6) of this section where combustible dust hazards are present.
1 Except no pictogram is required for explosives that are I .4S small arms ammunition and components thereof. Labels for I .4S small arms ammunition and components shall include appropriate precautionary statements.
2 The chemical manufacturer or importer shall label chemicals that are shipped in dust form, and present a combustible dust hazard in that form when used downstream, under paragraph (f)(1); 2) the chemical manufacturer or importer shipping chemicals that are in a form that is not yet a dust must provide a label to customers under paragraph (f)(4) if, under normal conditions of use, the chemicals are processed in a downstream workplace in such a way that they present a combustible dust hazard; and 3) the employer shall follow the workplace labeling requirements under paragraph (f)(6) where combustible dust hazards are present.
[61 FR 9227, March 7, 1996; 77 FR 17824, March 26, 2012; 89 FR 44395-44459, May 20, 2024; 89 FR 81833-81836, Oct. 9, 2024]