Beryllium
Exposure Evaluation and Controls
Exposure to beryllium via inhalation of airborne beryllium or dermal contact with beryllium-containing dust, fume, mist or solutions can cause health effects. The following resources provide information on exposure limits and analytical methods used to evaluate workers’ beryllium exposure.
Evaluating Exposures
The OSHA Occupational Chemical Database is OSHA's premier one-stop shop for occupational chemical information. It compiles information from several government agencies and organizations. Information available on the pages includes chemical identification and physical properties, exposure limits, sampling information, and additional resources.
Analytical Methods
OSHA
OSHA has developed and validated methods for use by the Salt Lake Technical Center (SLTC) laboratory. The following methods for sampling and measuring metal and metalloid particulates, including beryllium, have also been adopted by many laboratories.
- Beryllium and Compounds (as Be) (ICP Analysis). OSHA Method 1023, (June 2018). Describes collection and analysis of airborne beryllium, surface wipe and bulk sampling by inductively coupled plasma optical emission spectrometry (ICP-OES) instrumentation.
National Institute for Occupational Safety and Health (NIOSH):
- NIOSH Manual of Analytical Methods (NMAM). NMAM is a collection of methods for sampling and analysis of contaminants in workplace air, and in the blood and urine of workers who are occupationally exposed. NMAM also includes chapters on quality assurance, sampling, portable instrumentation, etc.
ASTM International Standards
- Determination of Elements in Airborne Particulate Matter by Inductively Coupled Plasma-Mass Spectrometry. Method D 7439-08. Comparable to OSHA ID-125G.
- Determination of Beryllium in the Workplace Using Field-Based Extraction and Optical Fluorescence Detection. Method D7202-11. Comparable to NIOSH 7704 / NIOSH 9110.
Controlling Exposure
Workers are primarily exposed to beryllium by breathing in dusts, fumes, or mists containing beryllium. Beryllium compounds can also get on the skin, contaminate clothing or food, and be ingested. The most effective way to prevent exposure to a hazardous metal such as beryllium is through elimination or substitution with viable, less toxic alternatives or through the use of engineering controls. The hierarchy of controls describes the order that should be followed when choosing among exposure-control options for a hazardous substance. Generally, elimination or substitution is the preferred choice (most protective) at the top of the hierarchy, followed by engineering controls, administrative and work-practice controls, and, finally, personal protective equipment (PPE). Engineering controls include isolating the source of exposure and using local exhaust ventilation to remove the hazardous substance before it enters the worker's environment. Administrative and work-practice controls include limiting the amount of time a worker performs work involving potential exposure to beryllium and proper cleaning and housekeeping methods, including the use of HEPA vacuuming and wet mopping instead of dry sweeping. PPE includes wearing the proper respiratory protection and protective clothing. These practices both limit worker exposure to beryllium in the workplace and help prevent beryllium contamination of workers' cars and homes.
The following list of resources provides information about beryllium and control methods that can be used to reduce and prevent exposure:
- Preventing Adverse Health Effects from Exposure to Beryllium in Dental Laboratories. OSHA Hazard Information Bulletin (HIB), (Revised May 2002; April 19, 2002). Informs employers and employees about the risk of dental laboratory technicians developing chronic beryllium disease (CBD). It also provides information on the ways in which beryllium exposures can be reduced and the type of protective equipment which can be worn to reduce exposure.
- NIOSH Pocket Guide to Chemical Hazards. National Institute for Occupational Safety and Health (NIOSH) Publication No. 2005-149, (September 2007). Provides physical description, exposure limits, measurement method, personal protection & sanitation, first aid, respirator recommendations, exposure routes, symptoms, target organs, and cancer sites.
- Beryllium & beryllium compounds (as Be). National Institute for Occupational Safety and Health (NIOSH) Pocket Guide to Chemical Hazards.
- Occupational Health Guidelines for Chemical Hazards. National Institute for Occupational Safety and Health (NIOSH) No. 81-123, (January 1981). Contains information on identification, physical and chemical properties, health hazards, exposure limits, exposure sources and control methods, monitoring, personal hygiene, storage, spills and leaks, and personal protective equipment.
- Beryllium. National Institute of Occupational Safety and Health (NIOSH) Workplace Safety and Health Topic. Provides links to sources of information on a variety of topics relating to beryllium.
- Beryllium Program - Beryllium at Hanford. Department of Energy Hanford. Provides information for Hanford employees who are concerned about beryllium. The information presented has been provided by site contractors.
- For additional information on general safety and health issues, see OSHA's Safety and Health Topics Pages on:
- For information on Safety Data Sheets and Labeling of hazardous materials, see OSHA’s Hazard Communication page.