Sampling and Analytical Methods - Withdrawn Methods

With the exception of withdrawn OSHA Method 7, withdrawn methods retain the validation status that applied at the time of publication based on OSHA’s then current validation guidelines. The validation data found in these withdrawn methods may still be useful. However, when making a determination regarding fitness for use, or when evaluating measurement uncertainty estimations, support for these methods is limited to the existing data. Any user of withdrawn OSHA methods should evaluate the potential need for additional independent data beyond what currently exists that may be required to validate a specific use.

Regarding Method 7, a determination was made to simply cite the NIOSH methods that formed the basis for the method. This method was never intended to cover analytes not listed in the method, nor other sampling and analysis approaches besides those specified. By reverting to the NIOSH methods in lieu of citing Method 7, we recognize the usefulness of the NIOSH methods, while indicating that OSHA Method 7 was never intended to apply to analytes not listed there, nor to other sampling media, desorption solvents, or other desorption approaches.

List of substances and methods
Substance
1,2,3-TRICHLOROPROPANE [7] Withdrawn
2,4-TOLUENE-DIISOCYANATE [18] Withdrawn
2,4-TOLUENE-DIISOCYANATE [33] Withdrawn
2,4-TOLUENE-DIISOCYANATE [42] Withdrawn
2-CHLOROPYRIDINE [PV2320] Withdrawn
ACETIC ACID [ID-186SG] Withdrawn
ACETIC ANHYDRIDE [82] Withdrawn
ACETOIN [1013] Withdrawn
ACRYLAMIDE [21] Withdrawn
ACRYLIC ACID [28] Withdrawn
ALLYL CHLORIDE [7] Withdrawn
ALUMINUM, METAL (as Al) [ID-204] Withdrawn
AMMONIUM SULFAMATE [ID-204] Withdrawn
ARSENIC, ORGANIC COMPOUNDS [ID-105] Withdrawn
BARIUM SULFATE [ID-204] Withdrawn
BENZENE [12] Withdrawn
BENZYL CHLORIDE [7] Withdrawn
BROMOFORM [7] Withdrawn
CADMIUM [ID-189] Withdrawn
CALCIUM CARBONATE [ID-204] Withdrawn
CALCIUM SILICATE [ID-204] Withdrawn
CALCIUM SULFATE [ID-204] Withdrawn
CAMPHOR [7] Withdrawn
CARBON MONOXIDE [ID-209] Withdrawn
CHLORINE DIOXIDE [ID-126SGX] Withdrawn
CHLORINE [ID-126SGX] Withdrawn
CHLOROBENZENE [7] Withdrawn
CYCLOHEXANE [7] Withdrawn
CYCLOHEXANOL [7] Withdrawn
CYCLOHEXENE [7] Withdrawn
DIACETYL [1013] Withdrawn
DIACETYL [PV2118] Withdrawn
DICYCLOPENTADIENYL IRON [ID-204] Withdrawn
DIFLUORODIBROMOMETHANE [7] Withdrawn
DIPHENYLAMINE [22] Withdrawn
DIPROPYL KETONE [7] Withdrawn
EMERY (CORUNDUM) [ID-204] Withdrawn
ETHYL ACETATE [7] Withdrawn
ETHYL ALCOHOL (ETHANOL) [100] Withdrawn
ETHYL BENZENE [7] Withdrawn
ETHYL BROMIDE [7] Withdrawn
ETHYL FORMATE [7] Withdrawn
ETHYLENE OXIDE [30] Withdrawn
ETHYLENE OXIDE [49] Withdrawn
ETHYLENE OXIDE [50] Withdrawn
FORMALDEHYDE [ID-205] Withdrawn
FORMIC ACID [ID-186SG] Withdrawn
GYPSUM [ID-204] Withdrawn
HEPTANE [7] Withdrawn
HEXACHLOROETHANE [7] Withdrawn
HEXANE (N-HEXANE) [7] Withdrawn
HEXANE (N-HEXANE) [PV2248] Withdrawn
HYDROGEN PEROXIDE [ID-006] Withdrawn
HYDROGEN PEROXIDE [ID-126SG] Withdrawn
HYDROGEN SULFIDE [ID-141] Withdrawn
ISOBUTYL ACETATE [7] Withdrawn
ISOPHORONE DIISOCYANATE [PV2034] Withdrawn
ISOPHORONE [7] Withdrawn
ISOPROPYL ACETATE [7] Withdrawn
ISOPROPYL ALCOHOL (2-PROPANOL) [ID-109SG] Withdrawn
KAOLIN [ID-204] Withdrawn
L-THYROXINE [PV2117] Withdrawn
LIMESTONE (NATURALLY OCCURING) [ID-204] Withdrawn
MALEIC ANHYDRIDE [25] Withdrawn
MARBLE [ID-204] Withdrawn
MESITYL OXIDE [7] Withdrawn
METHYL ACETATE [7] Withdrawn
METHYLCYCLOHEXANE [7] Withdrawn
N-BUTYL ACETATE [7] Withdrawn
N-NITROSODIETHYLAMINE [13] Withdrawn
N-NITROSODIMETHYLAMINE [6] Withdrawn
N-NITROSOMORPHOLINE [17] Withdrawn
N-PROPYL ACETATE [7] Withdrawn
O-DICHLOROBENZENE [7] Withdrawn
OCTANE [7] Withdrawn
OCTANE [PV2138] Withdrawn
OIL MISTS, MINERAL [ID-128] Withdrawn
P-DICHLOROBENZENE [7] Withdrawn
P-TERT-BUTYLTOLUENE [7] Withdrawn
PENTANE [7] Withdrawn
PHOSPHINE [ID-180] Withdrawn
PLASTER OF PARIS [ID-204] Withdrawn
PORTLAND CEMENT [ID-204] Withdrawn
PYRIDINE [7] Withdrawn
ROUGE [ID-204] Withdrawn
SEC-AMYL ACETATE [7] Withdrawn
SEC-BUTYL ACETATE [7] Withdrawn
SELENIUM & COMPOUNDS [ID-133SG] Withdrawn
SILICON CARBIDE [ID-204] Withdrawn
SILICON [ID-204] Withdrawn
SULFUR DIOXIDE [ID-104] Withdrawn
SULFUR DIOXIDE [ID-200] Withdrawn
TELLURIUM METAL & COMPOUNDS [ID-132SG] Withdrawn
TERT-BUTYL ACETATE [7] Withdrawn
TETRAHYDROFURAN [7] Withdrawn
TITANIUM DIOXIDE [ID-204] Withdrawn
VINYL TOLUENE [7] Withdrawn
ZINC STEARATE [ID-204] Withdrawn
ZINC STEARATE [ID-220SG] Withdrawn
ZIRAM [PV2073] Withdrawn
α-ALUMINA (ALUNDUM) [ID-204] Withdrawn